I'd not seen the show before last night, so I don't know what the chemistry is "supposed" to be like, but I thought the two had a very, well, I guess you could say, cute connection. It worked pretty well considering the parameters of the characters.
On the topic of the glasses, they were definitely Clark Kent-ish. Or maybe Buddy Holly-ish. It's nice that they are period-looking, but they are kind of distracting.
'"Contrairiwise," continued Tweedledee, "if it was so, it might be; and if it were so, it would be; but as it isn't, it ain't. That's logic."'
~Lewis Carroll